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Synthesis of partially saturated dipyrido[l,2-a:4,3-d] pyrimidin-11-ones via catalytic hydrogen-transfer reaction

✍ Scribed by Ferenc Fülöp; Imre Huber; György Dombi; Gábor Bernáth


Book ID
104205110
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
331 KB
Volume
43
Category
Article
ISSN
0040-4020

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✦ Synopsis


heterocycles,


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## Abstract By heating 2‐chloromethyl‐3,‐5‐dimethyl‐4‐methoxypyridine **(1)** either neat or in solution methoxy group cleavage was achieved, followed by dimerisation to poorly soluble 6,12‐dihydro‐1,3,7,9‐tetramethyl‐5__H__,11__H__‐dipyrido[1,2‐a:1′,2′‐d]pyrazine‐2,8‐dione **(3)** in almost quanti