Synthesis of p-tert-Butylthiacalix[4]arene and its Inclusion Property
โ Scribed by Nobuhiko Iki; Chizuko Kabuto; Takanori Fukushima; Hitoshi Kumagai; Haruhiko Takeya; Setsuko Miyanari; Tsutomu Miyashi; Sotaro Miyano
- Book ID
- 108370750
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 229 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Although the reaction of p-tert-butylphenol with elemental sulfur in the presence of CsOH as a base catalyst yielded a complex mixture comprised of sulfur-bridged phenol oligomers, p-tert-butylthiacalix[6]arene (TC6A) could be isolated in an appreciable yield (0.8%). The X-ray analysis revealed that
The synthesis of tetrathiacalix [4]arene was achieved by the detertiobutylation of p-tert-butyltetrathiacalix[4]arene. X-ray diffraction studies revealed that in the solid state whereas p-tert-butyltetrathiacalix[4]arene forms inclusion complexes with solvent molecules, tetrathiacalix[4]arene under