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Synthesis of p -Quinquephenyl from E,E -1,4-Bis(4-bromophenyl)-1,3-butadiene

✍ Scribed by Davis, Matthew C.; Groshens, Thomas J.


Book ID
120554370
Publisher
Taylor and Francis Group
Year
2010
Tongue
English
Weight
268 KB
Volume
41
Category
Article
ISSN
0039-7911

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Chiral (E,E)-1,4-dialkoxy-1,3-butadienes
✍ Marina Virgili; Albert Moyano; Miquel A. PericΓ s; Antoni Riera πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 209 KB

A two step, totally stereoselective synthesis of (E,E)-lA-dialkoxy-l,3-butadienes from chiral secondary alcohols has been developed. The key step involves the regio-and stereoselective hydrozirconation of alkoxyethynes derived from chiral alcohols; the intermediate (E)-(2alkoxyvinyl)zircouium compou