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Synthesis of oxygenated heterocycles from cyclic allylsiloxanes using ring-closing olefin metathesis

✍ Scribed by Christophe Meyer; Janine Cossy

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 180 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)10147-2

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✦ Synopsis

Cyclic ailylsiloxanes were prepared from allyldimethylsilyl ethers of various aikenols by using a catalytic ring-clusing metathcsis (RCM) reaclion. The transformation of these cyclic ailyls/loxanes into stereuseiectively substituted tetrahydrofurans and tetrahydropyrans was achieved by using a silyl modified Sakurai reaction.

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