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Synthesis of oxo- and methylene-bridged C60 dimers, the first well-characterized species containing fullerene-fullerene bonds.

✍ Scribed by Smith, Amos B.; Tokuyama, Hidetoshi; Strongin, Robert M.; Furst, George T.; Romanow, William J.; Chait, Brian T.; Mirza, Urooj A.; Haller, Ivan

Book ID: 115488195
Publisher: American Chemical Society
Year: 1995
Tongue: English
Weight: 284 KB
Volume: 117
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00141a031

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## Abstract Oxidation of the carboranyliridium fullerene complex [(η^2^‐C~60~)Ir(__o__‐HCB~10~H~9~CCH~2~PPh~2~‐__B__,__P__)(__t__BuNC)~2~] (I) in CHCl~3~ solution by O~2~ occurs by a selective insertion of the dioxygen molecule into the longest Ir−C bond (in the __trans__‐position relative to the B