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Synthesis of organolithium compounds from phenyl selenides

โœ Scribed by Alain Krief; Abdesslame Nazih; Myriam Hobe

Book ID
103408825
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
241 KB
Volume
36
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Synthesis of protected allylic amines fr
Synthesis of protected allylic amines from allylic phenyl selenides: Improved conditions for the chloramine T oxidation of allylic phenyl selenides
โœ John E. Fankhauser; Richard M. Peevey; Paul B. Hopkins ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 230 KB

Anhydrous chloramine T in methanol is a highly effective reagent for the conversion of allylic phenyl selenides to the corresponding rearranged N-allylic-p-toluenesulfonamides. The reaction presumably proceeds via an allylic selenimide intermediate which undergoes [2,3]sigmatropic rearrangement. The