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Synthesis of organogelling, fluoride ion-responsive, cholesteryl-based benzoxazole containing intra- and intermolecular hydrogen-bonding sites

✍ Scribed by Tae Hyeon Kim; Na Young Kwon; Taek Seung Lee


Book ID
104098230
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
744 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis


A cholesteryl-based 2-(2 0 -hydroxyphenyl)benzoxazole (HPB) derivative 3 linked with an amide bond was prepared through an efficient synthetic pathway. The HPB, amide, and cholesteryl groups play important roles in constructing the supramolecular gel structure. UV-vis and fluorescence spectroscopy also showed that HPB and amide groups, which provide intra-and intermolecular hydrogen bonding, respectively, also contribute the recognition of fluoride anions.