Synthesis of organic–inorganic polymer hybrids from poly(vinyl chloride) and polyhedral oligomeric silsesquioxane via CH/π interaction
✍ Scribed by Takeru Iwamura; Kaoru Adachi; Masato Sakaguchi; Yoshiki Chujo
- Book ID
- 113859071
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 508 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0033-0655
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## Abstract Organic/inorganic polyrotaxanes were synthesized via Huisgen 1,3‐dipolar cycloaddition between 3‐azidapropylhepta(3,3,3‐tri__fluoro__propyl) POSS and dialkyne‐terminated PEO/__α__‐cyclodextrin polypseudorotaxanes. The organic/inorganic hybrid polyrotaxanes were characterized by means of
## Abstract A new class of organic‐inorganic hybrid polymers with well‐defined structure was prepared by reacting diepoxyhexavinyl polyhedral oligomeric silsesquioxanes (DehvPOSS) with diamines of different chain lengths. The structures and properties of these hybrid polymers were well characterize