Synthesis of Optically Pure Terminal Epoxide and 1,2‐Diol via Hydrolytic Kinetic Resolution Catalyzed by New Heterometallic Salen Complexes
✍ Scribed by Singh Thakur, Santosh; Chen, Shu‐Wei; Li, Wenji; Shin, Chang‐Kyo; Koo, Yoon‐Mo; Kim, Geon‐Joong
- Book ID
- 127368639
- Publisher
- Taylor and Francis Group
- Year
- 2006
- Tongue
- English
- Weight
- 237 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0039-7911
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## Abstract The synthesis of chirally pure __β__‐blockers was successfully achieved __via__ hydrolytic kinetic resolution of butyl (±)‐4‐(oxiran‐2‐ylmethoxy)benzeneacetate ((±)‐**1**) and (±)‐4‐(oxiran‐2‐ylmethoxy)benzeneacetonitrile ((±)‐**2**) in the presence of bimetallic chiral [Co(salen)]‐type