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Synthesis of Optically Pure Arylsilylcarbinols and Their Use as Chiral Auxiliaries in Oxacarbenium Ion Reactions

✍ Scribed by Huckins, John R.; Rychnovsky, Scott D.


Book ID
126967344
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
213 KB
Volume
68
Category
Article
ISSN
0022-3263

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An optically pun aeamim amine was first synthesized fiom Glysine utilizing anodic oxidatim as a key step. andi~usefulnesswasexemplifiedbythcasymmetricMannichreactientogiveopticallyectiveBaminoacid tsters. Asymmetric tmnsfcr of amino group frwm amines substituted with chiral auxiky is a convenient sy