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Synthesis of Optically Active α-Hydroxyalkylphosphonates

✍ Scribed by O. I. Kolodyazhnyi; I. V. Gulyaiko


Book ID
111608440
Publisher
Springer
Year
2003
Tongue
English
Weight
53 KB
Volume
73
Category
Article
ISSN
1070-3632

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Synthesis of optically active α-sulfinyl
✍ P. Pflieger; C. Mioskowski; J.P. Salaun; D. Weissbart; F. Durst 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 197 KB

Recently several groups have utilized chiral P-hydroxysulfoxides 2 lm4, via the corresponding P-ketosulfoxides 3, for the synthesis of optically active epoxides 4 and secondary alcohols 5. Both antipodes of the epoxide and alcohol are accessible from the same P-ketosulfoxide B by stereoselective red