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Synthesis of Optically Active Macromolecules Using Metallocene Catalysts

✍ Scribed by Dr. Jun Okuda


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
269 KB
Volume
31
Category
Article
ISSN
0044-8249

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## Abstract The reduction of dimenthyl ketophosphonates with sodium borohydride involves asymmetric induction at the α‐carbon atom, resulting in a small excess of the (R)‐enantiomer of the α‐hydroxyphosphonate formed. A higher ee purity was achieved if the reduction of chiral dimenthyl ketophosphon