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Synthesis of optically active dendritic binaphthols and their metal complexes for asymmetric catalysis

✍ Scribed by Shigeru Yamago; Makoto Furukawa; Akira Azuma; Jun-ichi Yoshida

Book ID
108386746
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
246 KB
Volume
39
Category
Article
ISSN
0040-4039

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Synthesis of optically active polymers with chiral units attached to rigid backbones and their application for asymmetric catalysis
✍ Qiao-Sheng Hu; Chaode Sun; Colleen E Monaghan πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 70 KB

Optically active ephedrine-bearing poly(phenylene)s have been synthesized by using the Suzuki coupling polymerization. Their application as polymeric chiral catalysts for asymmetric addition of diethylzinc to aldehydes has been studied and good enantioselectivity was observed. The strategy to synthe