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Synthesis of optically active analogs of α-tocopherol based on (S)-(+)-dihydromyrcene

✍ Scribed by V. N. Odinokov; A. Yu. Spivak; G. A. Emel'yanova; E. V. Syutkina; Z. I. Ushakova; L. M. Khalilov

Book ID
105595636
Publisher
Springer
Year
2000
Tongue
English
Weight
302 KB
Volume
49
Category
Article
ISSN
1573-9171

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Highly enantioselective synthesis of (2R)-a-(hydroxymethyl)glutamate (1), a selective agonist of mGluR2 and 3, was achieved in short steps using an asymmetric version of the Strecker synthesis. This was converted into its a-methoxymethyland a-benzyloxymethyl derivatives 2 and 3, possible ligands as