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Synthesis of Optically Active 9-Oxabicyclo[3.3.1]nona-2,6-diene as a Cycloocta-1,5-diene Equivalent and the Corresponding Tetrol

✍ Scribed by Akira Takahashi; Mariko Aso; Masakazu Tanaka; Hiroshi Suemune

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 260 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00089-2

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✦ Synopsis

AbstractÐHighly enantio-and diastereo-selective synthesis of C 2 -symmetric 9-oxabicyclo[3.3.1]nona-2,6-diene and the corresponding C 2 -symmetric 2,3,6,7-tetrol has been achieved starting from optically active 5-cyclooctene-1,2-diol prepared by an enzymatic procedure.

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