Synthesis of Oligomeric and Polymeric Monosaccharides by Aldol Group-Transfer Polymerization
✍ Scribed by Prof. Dr. Günter Wulff; Dipl.-Chem. Paul Birnbrich; Dr. Achim Hansen
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 326 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
pCalc-d= 1.34 g p(MoKa)= 10.59 cm-', Enraf-Nonius diffractometer; 9318 measured reflections, averaged to 4352, 3083 observed reflections (I>2o(I)); R=0.029, R, ~0 . 0 3 8 ( w = l / 0 2 ( F o ) ) for I15 parameters [Sc]; b) crystal structure analysis of 5: Cl6H3,C1P,Rh, space group
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Oligomers covering degrees of polymerization up to 23 of 2-(1-imidazolyl)ethyl methacrylate (ImEMA) were synthesized by group transfer polymerization (GTP) in propylene carbonate and tetrahydrofuran (THF). While GTP proceeds smoothly in propylene carbonate, polymerization in THF is accompanied by ol