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Synthesis of Olefins from Sulfenes and Diazoalkanes via Episulfones

✍ Scribed by Priv.-Doz. Dr. G. Opitz; Dipl.-Chem. Klaus Fischer


Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
123 KB
Volume
4
Category
Article
ISSN
0044-8249

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Starting from the diaminodiphosphanes 1 and 21Za1 we have now succeeded in synthesizing the tetraphosphabicyclobutane system (4a, b) by PP-coupling to give the tetraphosphane 3 and subsequent cyclizing amine-elimination.