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Synthesis of olefins by anodic oxidation of vicinal dicarboxylic acids

โœ Scribed by H.H. Westberg; H.J. Dauben Jr.


Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
205 KB
Volume
9
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Recent studies in these laboratories concerned with the chemistry of homobarrelene derivatives necessitated finding a practical synthetic route to tricyclic compounds of type I (1).

The study described herein has shown that anodic oxidation of the vicinal dicarboxylic acids provides an easy method for introduction of the second double bond.

III

IV V


๐Ÿ“œ SIMILAR VOLUMES


Electrolytic decarboxylation of vicinal
โœ Phillip Radlick; Robert Klem; Steven Spurlock; James J. Sims; Eugene E. van Tame ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 233 KB

The familiar method for conversion of 1,2\_dicarboxylic acids to olefins is treatment with lead tetraacetate. However, this method suffers from low, vari-