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Synthesis of octyl 2-O-α-d-mannopyranosyl-α-d-mannopyranoside, its 6′-phosphate and the corresponding monomethyl phosphodiester: intermediate structures in the biosynthesis of N-linked oligosaccharides in Dictyostelium discoidium

✍ Scribed by Christer Hällgren; Ole Hindsgaul


Book ID
102996355
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
724 KB
Volume
260
Category
Article
ISSN
0008-6215

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✦ Synopsis


Octyl 2-O-cY-o-mannopyranosyl_cY-D-mannopyranoside, its 6'-phosphate and the corresponding 6'-methyl phosphodiester have been chemically synthesized. The latter compound was prepared using an H-phosphonate intermediate. These structures are for use as enzyme substrates and reference standards in a study on the biosynthesis of phosphorylated N-linked glycoproteins in the amoebae Dictyostelium discoideum.