✦ LIBER ✦

Synthesis of novel primary amino-terminated polymer and application for macromonomer

✍ Scribed by Koji Ishizu

Book ID: 105337544
Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 435 KB
Volume: 28
Category: Article
ISSN: 0887-624X
DOI: 10.1002/pola.1990.080280720

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✦ Synopsis

Abstract

The carboxyl‐terminated polystyrene (PS) was prepared by free radical polymerization of styrene initiated by functional azo‐initiator under a unimolecular termination mechanism. After replacement of the hydroxyl group of acids by chlorine, the end‐capping reaction of acyl halide‐terminated PS with a large excess of 1,6‐diaminohexane was carried out to obtain primary amino‐terminated PS. Subsequently, various PS macromonomers were derivated from primary amino‐terminated PS.

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