Synthesis of novel organosilicon-containing oligomers with reactive functional groups through anionic polycondensation reactions

Synthesis of end-functionalized polymer

Synthesis of end-functionalized polymer by means of living anionic polymerization, 5. Syntheses of polystyrenes and polyisoprenes with hydroxy and mercapto end groups by reactions of the living polymers with haloalkanes containing silyl ether and silyl thioether functions

✍ Mieko Tohyama; Akira Hirao; Seiichi Nakahama; Katsuhiko Takenaka 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 773 KB

## Abstract Anionic living polystyrene and polyisoprene were allowed to react with six __tert__‐butyl‐dimethylsilyl ethers of ω‐halo‐1‐alkanols 1–6, the trimethylsilyl ether of bromohydrin (7), the __tert__‐butyldimethylsilyl ether of 4‐bromophenol (8), and __tert__‐butyldimethylsilyl 3‐chloropropy