Synthesis of novel macrocyclic di- and tetralactams containing triazole subunits
✍ Scribed by Ahmed H. M. Elwahy; Ashraf A. Abbas; Refaie M. Kassab
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 132 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1042-7163
- DOI
- 10.1002/hc.10191
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✦ Synopsis
Abstract
The new macrocyclic di‐ and tetralactams 9, 15, and 16 were obtained in 16–24% yields by heating the appropriate bis‐amines 7 or 8 with the corresponding bisaldehyde 5 or 14 in refluxing acetic acid under high‐dilution conditions. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:551–559, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10191
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A series of heteroannulenes 3a-f containing four subunits of isoindole, two 1,2,4-triazole moieties, and six aza bridges have been synthesized by dimerization of the corresponding metallated, three-unit intermediates 5a-f. All these 28 pi-electron triazolephthalocyanine derivatives coordinate two me