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Synthesis of novel hydrophobically modified water soluble polymers by ring-opening metathesis polymerization

✍ Scribed by Clare M. McArdle; James G. Hamilton; Edwina E. Law; John J. Rooney

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
431 KB
Volume
16
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

Ring‐opening metathesis polymerization has been used to prepare a series of water soluble polymers based on the Diels‐Alder adducts of furan and cyclopentadiene. Hydrophobically modified forms of these polymers were obtained either by copolymerization with 5‐decylbicyclo[2.2.1]hept‐2‐ene, post‐polymerization modification of the acid forms of the polymers with 1‐decylamine or chain transfer to 1‐hexadecene. Polymers were characterized by NMR specroscopy and viscometry.

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This paper reviews the possibilities of engineering novel macromolecular topologies via ªlivingº ring-opening metathesis polymerization (ROMP) of miscellaneous macromonomers. It is shown that multibranched polystyrene poly(ethylene oxide) and polybutadiene polymacromonomers of varying compactness an