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Synthesis of novel glycosyl phosphate analogues: Derivatives of an acceptor substrate for the Leishmania elongating α-d-mannopyranosylphosphate transferase

✍ Scribed by Andrew J. Ross; Adrian P. Higson; Michael A.J. Ferguson; Andrei V. Nikolaev

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
223 KB
Volume
40
Category
Article
ISSN
0040-4039

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✍ Vladimir S Borodkin; Michael A.J Ferguson; Andrei V Nikolaev 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 86 KB

An isosteric C-glycoside phosphono analogue of dec-9-enyl b-D-galactopyranosyl-( 14)-a-D-mannopyranosyl phosphate was synthesised and showed high biological activity in the Leishmania MPT assay. A one-step Horner-Emmons/Michael reaction was developed for the stereoselective preparation of a-D-mannos