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Synthesis of novel chiral bisoxazoline ligands with a spiro[4,4]-1,6-nonadiene skeleton

โœ Scribed by ZhaoBin Han; Zheng Wang; XuMu Zhang; KuiLing Ding

Book ID
107372191
Publisher
Springer
Year
2010
Tongue
English
Weight
658 KB
Volume
55
Category
Article
ISSN
1001-6538

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๐Ÿ“œ SIMILAR VOLUMES

Synthesis of new chiral bis(isoxazoline)
Synthesis of new chiral bis(isoxazoline) ligands containing spiro[5.5]undecane skeleton
โœ Midori A. Arai; Minori Kuraishi; Takayoshi Arai; Hiroaki Sasai ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 335 KB ๐Ÿ‘ 1 views

New chiral bis(isoxazoline) ligands bearing a spiro[5.5]undecane skeleton were designed and synthesized in five steps from diethyl malonate (3). These ligands showed a coordinating ability to Cu(II) as chiral ligands. A complex of (+)-(M\*,S\*,R\*)-[5.5]-SPRIX 2b and Cu(OTf)(2) catalyzed the conjuga