A series of new bulky monophosphite ligands were synthesized from axially chiral BINOL and highly sterically hindered adamantanecarbonyl chloride. These ligands were applied to the Cu-catalyzed asymmetric 1,4-conjugate addition of diethylzinc to cyclic enones and were found to have moderate enantios
✦ LIBER ✦
Synthesis of novel chiral bidentate hydroxyalkyl-N-heterocyclic carbene ligands and their application in palladium-catalyzed Mizoroki–Heck couplings and asymmetric addition of diethylzinc to benzaldehyde
✍ Scribed by Faraji, Laleh; Jadidi, Khosrow; Notash, Behrouz
- Book ID
- 121434287
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- French
- Weight
- 899 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0040-4039
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