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Synthesis of novel 5- and 6-substituted 3-arylidene-1,4-oxathiin-2(3H)-ones

โœ Scribed by Ogawa, Kazuo; Terada, Tadafumi; Yamazaki, Tomio; Yamada, Shozo; Honna, Takaji; Ohta, Shunsaku; Okamoto, Masao

Book ID
120911785
Publisher
Royal Society of Chemistry
Year
1985
Weight
808 KB
Category
Article
ISSN
1472-7781

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Electron impact induced fragmentation of
Electron impact induced fragmentation of dihydro-1,4-oxathiines. 1. 2,3-substituted 5,6-dihydro-1,4-oxathiines
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In the electron impact induced fragmentation of 2,3-disubstituted 5,6-dihydro-1,4-oxathiines, the cleavage of the heterocyclic ring proceeds through the retro Diels-Alder type of reaction. The further fragmentation of the resulting radical cation gives rise to substituted carbonyl or thiocarbonyl ca