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Synthesis of novel 3-hetaryl-substituted 6- and 8-hydroxybenzo[f]coumarin derivatives

✍ Scribed by Todor Deligeorgiev; Teodora Tsvetkova; Stefka Kaloyanova; Diana Ivanova; Iliana Timtcheva


Book ID
111240417
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
228 KB
Volume
126
Category
Article
ISSN
0557-9325

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## Abstract magnified image A new series of 3‐acyl‐6,7,8‐substituted coumarin derivatives has been synthesized in high yields (79–99%) and characterized by means of elemental analysis, mass spectrometry, IR, and ^1^H NMR spectroscopy. We examined with particular attention the presence of an acyl gr

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## Abstract magnified image Condensation of 4‐chloro‐2‐oxo‐2__H__‐chromene‐3‐carbonitrile (**1**) with heteroarylamines **2a‐d** in acetonitrile containing a catalytic amount of triethylamine followed by spontaneous intramolecular cyclization gave the novel coumarin derivatives **3a‐d**, respectiv