Non-proteinogenic amino acid synthesis:
Non-proteinogenic amino acid synthesis: Synthesis of β,γ-unsaturated α-amino acids from asparic acid
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Jack E Baldwin; Mark G Moloney; Michael North
📂
Article
📅
1989
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Elsevier Science
🌐
French
⚖ 609 KB
A general, stereospecific, synthesis of S,Y-unsaturated a-amino acids using the S-anion derived from aspartic acid is described . S,Y-Unsaturated amino acids have been found to be reversible or irreversible inhibitors of a number of enzymes,' and this has prompted a number of racemic syntheses of th