✦ LIBER ✦

Synthesis of n,n′-biquinolines by a coupling reaction of bromoquinolines using organonickel(0) complexes

✍ Scribed by Yolanda Benito; Laureano Canoira; J. Gonzalo Rodriguez

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 424 KB
Volume: 1
Category: Article
ISSN: 0268-2605
DOI: 10.1002/aoc.590010607

No coin nor oath required. For personal study only.

✦ Synopsis

Tris(triphenylphosphine)nickel(O)

(A) and a zerovalent pyridine-nickel complex (B) have been used as reagents for the coupling reaction of 3-, 6and 8-bromoquinolines: 3,3'-, 6-6'-and 8,8'-Biquinolines were obtained in quantitative yields when A was used as the coupling reagent. B gave always a mixture of the n,n'-biquinoline and substitution products. A mechanism can be outlined to explain the coupling reaction of bromoquinolines using zerovalent nickel complexes.

📜 SIMILAR VOLUMES

Oxidation of Silyl Enol Ethers by Using

Oxidation of Silyl Enol Ethers by Using IBX and IBX⋅N-Oxide Complexes: A Mild and Selective Reaction for the Synthesis of Enones

✍ K. C. Nicolaou; David L. F. Gray; Tamsyn Montagnon; Scott T. Harrison 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB 👁 2 views

Oxidation of Silyl Enol Ethers by Using

Oxidation of Silyl Enol Ethers by Using IBX and IBX⋅N-Oxide Complexes: A Mild and Selective Reaction for the Synthesis of Enones

✍ K. C. Nicolaou; David L. F. Gray; Tamsyn Montagnon; Scott T. Harrison 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 126 KB 👁 2 views

Synthesis and characterizations of N,N′-

Synthesis and characterizations of N,N′-bis(diphenylphosphino)-2-(aminomethyl)aniline derivatives: application of a palladium(II) complex as pre-catalyst in Heck and Suzuki cross-coupling reactions

✍ Murat Aydemir; Akın Baysal; Gülşen Öztürk; Bahattin Gümgüm 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 2 views

Iron(0), rhodium(I) and palladium(II) co

Iron(0), rhodium(I) and palladium(II) complexes with p-(N,N-dimethylaminophenyl) diphenylphosphine and the application of the palladium complex as a catalyst for the Suzuki–Miyaura cross-coupling reaction

✍ Chandan Sarmah; Malabika Borah; Pankaj Das 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 196 KB 👁 2 views

## Iron(0), rhodium(I) and palladium(II) complexes with p-(N,N-dimethylaminophenyl) diphenylphosphine and the application of the palladium complex

Synthesis of a Palladium(IV) Complex by

Synthesis of a Palladium(IV) Complex by Oxidative Addition of an Aryl Halide to Palladium(II) and Its Use as Precatalyst in a CC Coupling Reaction

✍ Prof. Dr. José Vicente; Prof. Dr. Aurelia Arcas; M. Sc. Francisco Juliá-Hernánde 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 276 KB 👁 2 views

Synthesis of a Palladium(IV) Complex by

Synthesis of a Palladium(IV) Complex by Oxidative Addition of an Aryl Halide to Palladium(II) and Its Use as Precatalyst in a CC Coupling Reaction

✍ Prof. Dr. José Vicente; Prof. Dr. Aurelia Arcas; M. Sc. Francisco Juliá-Hernánde 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 287 KB 👁 1 views