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Synthesis of New Sterically Hindered Anilines

โœ Scribed by Barry R. Steele; Spyros Georgakopoulos; Maria Micha-Screttas; Constantinos G. Screttas

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
92 KB
Volume
2007
Category
Article
ISSN
1434-193X

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While methylation of lithium cyclopropylcarbenoids is easy, their reaction with electrophilic cyclopentadienes causes serious problems. Cyclopentenone can be reacted with lithium cyclopropylcarbenoids bearing groups X of low steric requirement. G.