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Synthesis of new phosphonato esters by reaction between triphenyl or trialkyl phosphite and acetylenic diesters in the presence of NH-containing compounds

✍ Scribed by Ghasem Marandi; Malek Taher Maghsoodlou; Nourallah Hazeri; Reza Heydari; Sayyed Mostafa Habibi-Khorassani; Niloufar Akbarzadeh Torbati; Seyed Sajad Sajadikhah; Danial Saravani; Mansoureh Rakhshanipour; Samira Gholamipour; Faramarz Rostami-Charati; Brian W. Skelton; Mohamed Makha; Zeynab Zare; Mojtaba Lashkari


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
193 KB
Volume
22
Category
Article
ISSN
1042-7163

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✦ Synopsis


Abstract

The reaction between triphenyl or trialkyl phosphite and acetylenic esters in the presence of some heterocyclic or aromatic NH compounds such as thiazolidine‐2,4‐dione, 2‐methyl indole, 5‐bromoisatine, 3‐nitroacetanilide, saccharin, 5,5‐dimethylhydantoin, 2‐nitroaniline, 4‐nitroaniline, benzophenon hydrazine, and anthranilic acid led to the formation of phosphonato esters in high yield. © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:630–639, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20725


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Synthesis of aromatic amine phosphonato
✍ Malek Taher Maghsoodlou; Reza Heydari; Nourallah Hazeri; Sayyed Mostafa Habibi-K 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 200 KB

## Abstract Aromatic amine phosphonato esters **4a–d** were obtained in excellent yields from the 1:1:1 addition reaction between triphenyl phosphite and dimethyl acetylenedicarboxylate in the presence of NH‐aromatic amines such as 2‐aminobenzophenone, 2‐aminoacetophenon, methyl‐2‐aminobenzoate, an