## Abstract The isocoumarin derivative 1__H__‐1‐acetylimino‐3‐methylbenzo[c]pyran‐4‐carbonitrile reacts with 1,8‐naphthalenediamine under basic conditions to give, primarily, 12‐acetylisoquino[2,1‐__a__]perimidin‐13‐amine. This undergoes a variety of reactions to give other isoquino[2,1‐__a__]perim
✦ LIBER ✦
Synthesis of new perimidine derivatives from the reaction of 1,8-diaminonapthalene with iminoester hydrochlorides
✍ Scribed by Kahveci, Bahittin; Karaali, Nesrin; Menteşe, Emre; Yılmaz, Fatih
- Book ID
- 125487226
- Publisher
- SAGE Publications
- Year
- 2013
- Tongue
- English
- Weight
- 78 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1747-5198
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## Abstract The reaction of 1,3‐diphenyl‐2‐(phenylimino)‐3‐(ylidenemethyl‐acetate)‐1‐propanone **(5)** with trisdialkylaminophosphines **(6a,b)** in refluxing toluene afforded the new oxazaphospholene products **(7a–b)**. On the other hand, the cyclic azaphospholene adducts **8a–b** were isolated f