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Synthesis of new olean-18(19)-ene derivatives from allobetulin

โœ Scribed by O. B. Kazakova; E. F. Khusnutdinova; G. A. Tolstikov; K. Yu. Suponitsky


Book ID
111457099
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
247 KB
Volume
36
Category
Article
ISSN
1068-1620

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We report the total synthesis of the racemlc /l -amyrin derivatives olean-13(18)-ene (XII) and l&r-olesn-12-ene (XIII) by a direct route, not involving relays. Trevious syntheses of fl -amyrin derivatives using natural materials as relays have been described4. Condensation of the Grignard derivativ