Synthesis of New NHC—Rhodium and Iridium Complexes Derived from 2,2′-Diaminobiphenyl and Their Catalytic Activities Toward Hydrosilylation of Ketones.
✍ Scribed by Tao Chen; Xu-Guang Liu; Min Shi
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 24 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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A group of a diverse family of dinuclear copper(II) complexes derived from pyrazole-containing tridentate N 2 O ligands, 1,3-bis(3,5-dimethylpyrazol-1-yl)propan-2-ol (Hdmpzpo), 1,3-bis(3-phenyl-5-methyl pyrazol-1-yl)propan-2-ol (Hpmpzpo) and 1,3-bis(3-cumyl-5-methylpyrazol-1-yl)propan-2-ol (Hcmpzpo)
## Abstract Reaction of (__R__)‐bis(pyrrol‐2‐ylmethyleneamino)‐1,1′‐binaphthyl (1H~2~) or (__R__)‐__N__,__N′__‐bis(pyridin‐2‐ylmethyl)‐1,1′‐binaphthyl‐2,2′‐diamine (2H~2~) with Zr(NMe~2~)~4~ (1 equiv.) gives chiral zirconium amides 1‐Zr(NMe~2~)~2~·C~7~H~8~ (4·C~7~H~8~) or 2‐Zr(NMe~2~)~2~ (6) in goo