✦ LIBER ✦

Synthesis of new deazaflavins with planar chirality. Redox-induced “rope-skipping” racemization

✍ Scribed by Seiji Shinkai; Toshiro Yamaguchi; Hideki Nakao; Osamu Manabe

Book ID: 104218410
Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 223 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84327-0

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✦ Synopsis

New S-deazaflavins with planar chirality (dFl(n)) were synthesized in which N(3) and O(Z'a) in the lo-(2'-hydroxy)phenyl group were linked by a +CHZ+~ chain (n=E ,lO) . (+)-dFl(n=8) showed a large chiral discrimination in fluorescence quenching by (R)-and (S)-l,l'-bi-2naphthol.

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