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Synthesis of New Cyclophane Host Molecules and Crystal Structures of Their Compounds with Hydrocarbon Guests

✍ Scribed by N. Kent Dalley; Xiaolan Kou; Richard A. Bartsch; Piotr Kus


Book ID
110432486
Publisher
Springer Netherlands
Year
2003
Tongue
English
Weight
286 KB
Volume
45
Category
Article
ISSN
0923-0750

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An X-ray study of the adduct formed by hexakis(p-tbutylphenylthiomethyl)benzene (I) with squalene (II) establishes the first example of channel-type inclusion behaviour for a hexahost molecule, the guest triterpene (II) being observed in a novel conformation controlled by host-guest interactions. In