Synthesis of new copper(II) complexes of polydentate ligands containing pyridyl pendant arms. Crystal structure of [N, N, N′, N′-tetrakis(2-pyrid-2-yl-ethyl)1, 2-ethylenediaminecopper(II)]-bis(hexafluorophosphate) · 1.5 acetone
✍ Scribed by Nazario Marsich; Giorgio Nardin; Lucio Randaccio; Annamaria Camus
- Book ID
- 108331658
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 688 KB
- Volume
- 278
- Category
- Article
- ISSN
- 0020-1693
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📜 SIMILAR VOLUMES
## Abstract The stability constants of the Cu^II^ chelates with the tripodal heptadentate ligand tris{2‐[(2‐pyridylmethyl)amino]ethyl}amine (=__N__′‐(pyridin‐2‐ylmethyl)‐__N,N__‐bis{2‐[(pyridin‐2‐ylmethyl)amino]ethyl}ethane‐1,2‐diamine; tpaa), determined by potentiometry and UV spectrometry, show t
Two new polynuclear complexes of Cu II , [Cu 2 (fum)(µ-OH)(bpy) 2 (H 2 O)](NO 3 )•2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]•2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.