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Synthesis of new bismuth complexes [Ph3MeP]6[BiI3Br3][Bi2I6Br3]H2O2and [Ph3MeP]6[BiI3Br3][Bi2I6Br3]

✍ Scribed by V. V. Sharutin; I. V. Egorova; A. P. Pakusina; O. K. Sharutina; M. A. Pushilin

Book ID: 111458992
Publisher: Springer
Year: 2006
Tongue: English
Weight: 18 KB
Volume: 76
Category: Article
ISSN: 1070-3632
DOI: 10.1134/s1070363206080329

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## Abstract New cluster compounds [H~3~O(Ph~3~PO)~3~]~2~[Mo~6~Cl~14~] (I) and [H(Ph~3~PO)~2~]~2~[Re~6~S~6~Br~8~] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph~3~PO with octahedral cluster complexes of molybdenum (H~3~O)~2~Mo~6~Cl~14~·6H~2~O and rh