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Synthesis of new bis(cyclopentadienyl)yttrium complexes with ether functionalized cyclopentadienyl ligands. Crystal structure of [(C5H4CH2CH2OMe)2Y(μ-H)2BH2]

✍ Scribed by Dietmar A. Laske; Robbert Duchateau; Jan H. Teuben; Anthony L. Spek


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
547 KB
Volume
462
Category
Article
ISSN
0022-328X

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The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4