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Synthesis of (+)-negamycin from D-glucose

✍ Scribed by Silvano De Bernardo; John P. Tengi; Gino Sasso; Manfred Weigele

No coin nor oath required. For personal study only.

✦ Synopsis

Summazy: The broad spectrum antibiotic (+)-negamycin (1) was prepared from 1,2-o-isopropylidene-D-glucose (3) in nine steps.

Negamycin ( 1) is a broad spectrum antibiotic elaborated by ~iepfOr?ltjCeb puip~O~ubcub.l

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