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Synthesis of naphthoquinone derivatives. 3. Cycloshikonin and its derivatives. A synthetic route to shikonin

✍ Scribed by Tanoue, Yasuhiro; Terada, Akira; Sugyo, Yasunari

Book ID
126436110
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
461 KB
Volume
52
Category
Article
ISSN
0022-3263

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## Abstract A new synthetic route for the synthesis of the nordasycarpidone derivative **11** which has hexahydro‐1,5‐methanoazocino[4,3‐__b__]indol skeleton, is described. Construction of the tetracyclic structure was achieved by catalytic reduction and cyclization reaction of the nitrile derivati