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Synthesis of Na+-montmorillonite/amphiphilic polyurethane nanocomposite via bulk and coalescence emulsion polymerization

โœ Scribed by Ju-Young Kim; Woo-Chul Jung; Kang-Yeol Park; Kyung-Do Suh


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
276 KB
Volume
89
Category
Article
ISSN
0021-8995

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Synthesis of novel amphiphilic pH-sensit
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Amphiphilic urethane acrylate anionomer (UAA) chains exhibited very different solution properties in various solvents, such as water, dioxane, and dimethyl sulfoxide (DMSO). UAA chains showed a polyelectrolyte effect in a highly polar solvent, DMSO, but gave constant viscosity at various concentrati

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pH-sensitive amphiphilic networks are synthesized from urethane acrylate anionomer (UAA) precursor chains. The microstructures of these networks are very sensitive to the nature of and the amount of solvent used during crosslinking. Whereas dioxane forms relatively homogenous solution, water prefere