Synthesis of N3-substituted methylexo-3,4-diazatricyclo[5.2.1.02,6]dec-4-ene-5-carboxylates
✍ Scribed by V. A. Gorpinchenko; D. V. Petrov; L. V. Spirikhin; V. A. Dokichev; Yu. V. Tomilov
- Book ID
- 111464166
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2006
- Tongue
- English
- Weight
- 429 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1070-4280
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.003 A Ê R factor = 0.047 wR factor = 0.144 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Base-catalysed rearrangement of a 2-alkynyl-tetrahydropyran generates an allenol ether intermediate which undergoes acid-catalysed cyclisation to the 1,6-dioxaspiro[4S]dec-3-ene system. We recently described a synthesis of the 1,7-dioxaspiro[5S]undec-4-ene system (4)' which made strategic use of th