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Synthesis of N-substituted oxazoline-2-thione derivatives: reaction of tetraazapentalene derivatives with α-haloketones

✍ Scribed by Noboru Matsumura; Masaaki Tomura; Osamu Mori; Yoshikazu Takamura; Shigeo Yoneda

Book ID
104229816
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
273 KB
Volume
30
Category
Article
ISSN
0040-4039

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## Abstract The reaction of __N__‐thioamido amidines **1** with tris(dimethylamino)phosphine or bis(diethylamino)phenylphosphine in refluxing toluene leads to the 1,3,5,2λ^3^‐triazaphosphorines **2** and **3**, respectively. The condensation results in the release of two molecules of dialkylamine.