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Synthesis of N-phytochlorin-substituted [60]fulleropyrrolidines

✍ Scribed by Alexander Efimov; Nikolai V. Tkatchenko; Pirjo Vainiotalo; Helge Lemmetyinen

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
82 KB
Volume
05
Category
Article
ISSN
1088-4246

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✦ Synopsis

A series of new phytochlorin–fullerene dyads was prepared. Synthetic pathway includes attachment of glycine to aldehyde-containing phytochlorins via reductive amination, where 3- and 7-carbonyl-substituted pheophorbides exhibit surprisingly different reactivity. The appropriate conditions of reactions (e.g. solvents and reducing agents) were determined in each case.

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