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Synthesis of n-butyl [3-13C]acrylate

✍ Scribed by J. Šmejkal; V. Hanuš; I. Linhart; T. Elbert

Publisher
John Wiley and Sons
Year
1990
Tongue
French
Weight
184 KB
Volume
28
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

A four step synthesis of n‐butyl [3‐^13^C]acrylate from [^13^C]methyl iodide is described. The procedure involves methylation of butyl acetoacetate, subsequent bromination, alkaline cleavage and, finally, dehydrobromination using cyclohexyldimethylamine. The overall yield was 5%.

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