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Synthesis of Multitopic Verdazyl Radical Ligands. Paramagnetic Supramolecular Synthons

✍ Scribed by Hicks, Robin G.; Koivisto, Bryan D.; Lemaire, Martin T.

Book ID: 111943167
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 97 KB
Volume: 6
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol049746i

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## Abstract The reaction between [Mn(MAC)(H~2~O)~2~]Cl~2~·4H~2~O and LiTCNQ (MAC = 2,13‐dimethyl‐3,6,9,12,18‐pentaazabicyclo[12.3.1]octadeca‐1(18),2,12,14,16‐pentaene) affords a complex with the formula [Mn(MAC)(TCNQ)~2~] (1), whose crystal structure has been determined. Its structure consists of n