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Synthesis of Multielectron Ligands for Transition Metals via Spiro[cyclopropane-1,1′-indene]

✍ Scribed by Karlheinz Berghus; Angelika Hamsen; Dipl.-Chem. Alfons Rensing; Annegret Woltermann; Prof. Dr. Thomas Kauffmann


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
226 KB
Volume
20
Category
Article
ISSN
0044-8249

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✍ Antonio Otero; Fernando Carrillo-Hermosilla; Pilar Terreros; Teresa Expósito; Se 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 182 KB 👁 1 views

## Abstract Modification of the multistep synthesis of the previously described bis[5‐(diphenylphosphanyl)pyrazol‐1‐yl)]methane (bppzm, 1) produces the novel diphosphane (diphenylphosphanyl)‐[5‐(diphenylphosphanyl)pyrazol‐1‐yl](pyrazol‐1‐yl)methane (p4m, 2). Treatment of this ligand with [MCl~2~(Ph