✦ LIBER ✦

Synthesis of MTW-type microporous material and its vanadium-silicate analogue using a new diquaternary ammonium cation as a template

✍ Scribed by Asim Bhaumik; M.K. Dongare; Rajiv Kumar

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 312 KB
Volume: 5
Category: Article
ISSN: 0927-6513
DOI: 10.1016/0927-6513(95)00051-a

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✦ Synopsis

A new organic template, 1,6-hexamethylene-bis(benzyldimethylamrnonium hydroxide), efficiently produced zeolite ZSM-12 and Al-free pure silica polymorph. The vanadium-silicate analogue, [V]-MTW, was also synthesized. These vanadium-silicate samples catalyze the oxidation of phenol, n-alkanes, cyclohexane, ethylbenzene, etc. using dilute H202 (30 wt.-%, aqueous)